supraspectra:

Top: Space Shuttle Atlantis docked with Mir on 4 July 1995.  Cosmonauts Anatoliy Y. Solovyev and Nikolai M. Budarin, who had arrive onboard Atlantis five days earlier, took Soyuz TM-21 for a fly-around photo survey prior to Atlantis undocking for her return to Earth.  This was the first time a shuttle had docked with Mir.

Bottom: Two shots of the Space Shuttle Endeavour docked with the ISS, as photographed by the departing Soyuz TMA-20 spacecraft on 23 May 2011, during the STS-134 mission.  (There are a lot more from this fly-around here)